Here is the list of the most well know free chat and webcam / video chat sites on the web. Make new friends, chat, meet people from all over the globe but remember these websites are very addictive.

http://shockrooms.com
http://chatroulette.com
http://www.chatforfree.org
http://tinychat.com
http://yapchat.com
http://www.userplane.com
http://www.freechatnow.com
http://planetlivechat.com
http://room7.com

Have fun!